XP-Anti-spy can aid in tweaking. Enable fast shutdown.
You also need to scan your computer for spyware (I use SpySweeper for example) and scan for viruses (I like NOD32 and AVG anti-viruses). You also need to defrag your system. Clean some crap up. I like Window Washer (from the same people who make SpySweeper) Webroot
black viper can help you with turning off services you don't need.
RegSeeker to clean the registry and do a little tweaking. It also allows you to take crap out of the startup registry. NTRegOpt also helps to optimize the registry. Don't forget to tweak your system with X-Setup
It should only take seconds to shut down your comp. ESPECIALLY on your hardware.
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