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seagates discwizard will format and partition any drive download it free HERE
edit... you need to turn off the pagefile, recycle bin and restore for the drive you wanna format before you do use the software, otherwise as soon as you reboot it windows will just re-allocate them to the drive, it may do it anyway coz xp thinks it is cleverer than us! if so just format with discwizard and then turn off the bin etc after reboot ;)
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why not reformat the whole thing, put xp on your smaller 6gig master drive. and have the 20gig as your backup drive. and download all your things on the 20gig drive, thats how i have my other pc setup, 2k on small 4gig drive, and 80gig slave drive.